Fractionation of hydrogen isotopes in crystal water of copper chloride dihydrate-saturated solution-water vapor system.

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Key words: Fractionation of hydrogen isotopes, Aqueous lithium chloride solution. Hydrophobic platinum catalyst, Dependence of D/H fractionation on molality, Comparison of hydrogen and oxygen isotope effects. Introduction

The D/H ratio of hydrogen gas in equilibrium with water vapor over aqueous lithium chloride solutions was measured at 25 °C, using a hydrophobic platinum catalyst. Experimental details are described. The hydrogen isotope effect between the solution and pure water depends linearly on the LiCl concentration up to ca. 12 m, and at higher concentrations a marked deviation from linearity takes place...

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ژورنال

عنوان ژورنال: GEOCHEMICAL JOURNAL

سال: 2001

ISSN: 0016-7002

DOI: 10.2343/geochemj.35.277